1) thioether palladium complex
硫醚钯配合物
1.
MCM-41-supported thioether palladium complex has been prepared via immobilization of 3-(2-cyanoethylsulfanyl)propyltriethoxysilane on MCM-41, followed by reacting with palladium chloride.
γ-(β-氰乙硫基)丙基三乙氧基硅烷依次用纳米介孔分子筛(MCM-41)固载、与氯化钯反应,合成了MCM-41负载硫醚钯配合物。
2) Sulfur palladium complex
硫钯配合物
3) Pd complex
钯配合物
1.
Studies of catalytic performance of mesoporous molecular sieve MCM-41 supported Pd complex;
MCM-41载钯配合物催化性能的研究
2.
Synthesis of fumed silica supported amino-Pd complexes and their catalytic performance for Heck reaction
气相法二氧化硅负载胺-钯配合物的制备及对Heck反应催化性能的研究
3.
Some new MCM-41 supported melamine polycondensated with formaldehyde polymer Pd complex catalysts are prepared and characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) techniques.
制备了一些新的MCM 41负载的三聚氰胺缩甲醛高分子钯配合物催化剂 ,并利用X 射线衍射 (XRD)和X 射线光电子能谱 (XPS)对催化剂进行了表征 。
4) Palladium complex
钯配合物
1.
The catalytic activity of palladium complex in coupling reaction of organotins and organic halides;
钯配合物对有机锡试剂和有机卤化物偶联反应的催化性能研究
2.
The palladium complex of 1, ^PdCl2(2-py)2NH^ (2), crystallizes in the monoclinic space group P21/n with a=10.
1的钯配合物[PdCl2(2-py)2NH](2)是以单斜空间群P21/n结晶,其晶胞参数为a=10。
3.
Catalyst for melamine formaldehyde resin-palladium complexes is prepared using MgO as solid supported material.
以MgO作为固载材料 ,制备了氧化镁负载三聚氰胺缩甲醛树脂—钯配合物催化剂。
6) palladium compounds
钯配合物
1.
Emphasis is laid on the application of some supported catalysts,such as palladium compounds supported on inorganic support,palladium salts and heteropolyacid supported on inorganic support,palladium salts supported on polymer in the oxidation of olefins to aldehyde and ketones.
着重介绍了钯配合物固载在无机载体上 ,钯盐和杂多化合物固载在无机载体上 ,钯盐固载在高分子载体上形成的固载化催化剂在烯烃氧化合成醛酮中的应用。
2.
The development in the oxidation of olefins to ketones catalyzed by palladium compounds was reviewed.
本文系统地评述了钯配合物催化烯烃氧化合成酮类物质的研究进展。
补充资料：乙炔型硫醚
分子式：
CAS号：
性质：通式为RSC≡CH及RSC≡CSR的化合物。其代表性物质如(1)乙炔基·苯基硫醚(acetylenyl phenyl thioether)CH≡CSC6H5，黄色液体，沸点78～79℃(933.254Pa)。折射率1.5938；(2)乙炔基·乙基硫醚C2H5SC≡CH，无色液体，沸点91.5～92℃。折射率1.4790。上述物质在室温下放置时均易发生变化，其反应性近似于碳数相同的炔醚类。被过乙酸(CH3COOH)氧化，即生成乙炔类的砜。其制法举例如下：(1) Cl2C=CHCl+3NaSC4H4→C4H9SC≡CSC4H9+3NaCl+C4H9SH(2) RSCH=CHBrRSC≡CH可用作有机合成试剂。
CAS号：
性质：通式为RSC≡CH及RSC≡CSR的化合物。其代表性物质如(1)乙炔基·苯基硫醚(acetylenyl phenyl thioether)CH≡CSC6H5，黄色液体，沸点78～79℃(933.254Pa)。折射率1.5938；(2)乙炔基·乙基硫醚C2H5SC≡CH，无色液体，沸点91.5～92℃。折射率1.4790。上述物质在室温下放置时均易发生变化，其反应性近似于碳数相同的炔醚类。被过乙酸(CH3COOH)氧化，即生成乙炔类的砜。其制法举例如下：(1) Cl2C=CHCl+3NaSC4H4→C4H9SC≡CSC4H9+3NaCl+C4H9SH(2) RSCH=CHBrRSC≡CH可用作有机合成试剂。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条