1) Coordination reaction
配位反应
1.
A novel technology about the integration of separation and coordination reaction of hesperidin with Cu2+ in ion-exchange chromatography(IEC) column was presented and performed in this paper.
提出并实现了橙皮苷分离及其与Cu2+配位反应一体化的新设想,并借助离子交换色谱、紫外可见光谱、X-射线衍射、傅立叶红外光谱和核磁共振等分析手段探讨其作用机理。
2.
The rate of the coordination reaction between divalent metal ions and murexide in a water-in-oil microemulsion was determined by spectrophotometric technique to study the transport of the metal ions entrapped in the organogel formed by cationic surfactant cetyltrimethylammoni.
以微乳液中二价金属离子与紫脲酸胺之间的配位反应为指示反应 ,采用分光光度技术 ,研究了金属离子在由阳离子表面活性剂十六烷基三甲基溴化胺构建的微乳凝胶中的传质问题 。
3.
Coordination reaction between H 2HAPP and metal ion Zn(Ⅱ) in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)=1∶1] solvent was studied by UV Vis spectroscopic method, which indicated 1∶1 complexing between H 2HAPP and Zn(II) ion occurred easily in such a homogeneous sys.
适合 H2 HAPP与金属离子配位反应动力学等研究的均。
2) coordinate reaction
配位反应
1.
The constant of action, activationenergy and some thermodynamic parameters on the coordinate reaction of letrabenzoporphine with Cu 2+ and Co 2+ were determimed by spectrometric methods.
用光度法测定了四苯骈卟啉与Cu2 + ,Co2 + 配位反应速率常数、活化能及热力学参数 。
2.
The rate constant, activation energy and some thermodynamic parameters on the coordinate reaction of bridged crowned porphyrin with Co2+ and Cu2+ were determined by spectrometric methods.
用光度法测定了桥链冠醚卟啉与Ｃｏ２＋、Ｃｕ２＋配位反应的速率常数、活化能及热力学参数。
3.
The effect of the structure of porphyrin on the coordinate reaction was disscussed and their Uv-Vis and fluorescence spectra were reported.
用光度法测定了３种取代四苯基卟啉与Ｃｏ２＋、Ｃｕ２＋配位反应的速率常数、活化能及热力学参数。
3) trans effect of ligand
配位体反位效应
4) homogeneous coordination reaction
均相配位反应
6) solid state coordination
固相配位反应
1.
The spinel LiMn 2O 4 was prepared by solid state coordination method which has never been reported heretofore.
采用固相配位反应法合成了锂离子电池阴极材料LiMn2 O4 ,研究了前驱体的热解行为以及温度、锂含量和配位体用量对LiMn2 O4 性能的影响。
补充资料：配位反应
分子式：
CAS号：
性质：由配位体通过配位键与中心原子（或离子）组成配位化合物的反应。在配位反应中配位体起配位作用，通常，在条件允许下，尽量满足中心原子的最大配位数。如二氯化铂与氰化钾生成四氰铁酸钾和氯化钾PtCl2+4KCN→K2[Pt(CN4)] +2KCl，形成的K2[Pt(CN4)2-满足中心离子d8构型Pt（II）的配位数，并为平面正方形型。
CAS号：
性质：由配位体通过配位键与中心原子（或离子）组成配位化合物的反应。在配位反应中配位体起配位作用，通常，在条件允许下，尽量满足中心原子的最大配位数。如二氯化铂与氰化钾生成四氰铁酸钾和氯化钾PtCl2+4KCN→K2[Pt(CN4)] +2KCl，形成的K2[Pt(CN4)2-满足中心离子d8构型Pt（II）的配位数，并为平面正方形型。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条