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1)  tert-butyl acrylate
丙烯酸叔丁酯
1.
Dispersion polymerization of tert-butyl acrylate(tBA)proceeded with ethanol-water solution as dispersion medium,polyvinylpyrrolidone(PVP)as stabilizer and azobisisobutyronitrile(AIBN)as initiator.
以偶氮二异丁腈为引发剂、聚乙烯基吡咯烷酮为稳定剂、乙醇-水混合溶剂为分散介质,对丙烯酸叔丁酯的分散聚合行为进行了研究。
2.
A series of temperature-sensitive microgels were synthesized using N-isopropylacrylamide(NIPAM) as main monomer,tert-butyl acrylate(tBA) as comonomer,and N,N′-methylene-bis(acrylamide)(MBA) as cross-linking agent by modified surfactant-free emulsion polymerization method.
以一定量的N-异丙基丙烯酰胺(N IPAM)为主单体,以亚甲基双丙烯酰胺(M BA)为交联剂,使用丙烯酸叔丁酯(tBA)为共聚单体,通过改进的无皂乳液聚合方法制备了具有温敏性的P(N IPAM-co-tBA)微凝胶。
3.
In the present dissertation, controlled grafting polymerization of styrene, methyl methacrylate (MMA), tert-butyl acrylate (tBA) by atom transfer radical polymerization from cross-linked poly(methyl methacrylate) microgel were carried out.
然后,在溴化亚铜(CuBr)/2,2′-联吡啶的催化下,以PMMA微凝胶粒子作为苯乙烯、甲基丙烯酸甲酯、丙烯酸叔丁酯原子转移自由基聚合的引发剂,成功的进行了苯乙烯、甲基丙烯酸甲酯、丙烯酸叔丁酯的接枝聚合。
2)  poly(tert-butyl acrylate)
聚丙烯酸叔丁酯
1.
The aim to synthesize the composite particles based on silica as core and poly(tert-butyl acrylate) as shell in this work, is to prepare the inorganic/organic core/shell composite particles whose shells are composed of poly(acrylic acid) by transforming poly(tert-butyl acrylate) into poly(acrylic acid) by hydrolysis.
本文采用分散聚合法制备内核为二氧化硅(SiO_2)、壳层为聚丙烯酸叔丁酯的核壳复合粒子,目的是想通过水解,使聚丙烯酸叔丁酯转变为聚丙烯酸,最后得到壳层为聚丙烯酸的无机/有机核壳复合粒子。
3)  poly(tert-butylmethacrylate)
聚甲基丙烯酸叔丁酯
1.
Core/shell composite microparticles with silica nanoparticle as core and crosslinked poly(tert-butylmethacrylate) as shell were prepared by seed-emulsion polymerization utilizing 3-(trimethoxysilyl)propyl methacrylate(MPS) modified silica particles as seeds,tert-butylmethacrylate as monomer and sodium dodecyl sulfate(SDS) as emulsifier.
以甲基丙烯酸-3-(三甲氧基硅基)丙酯(MPS)修饰的SiO2胶体粒子为种子,甲基丙烯酸叔丁酯(tBMA)为单体、十二烷基硫酸钠(SDS)为乳化剂,采用种子乳液聚合法制备了SiO2/聚甲基丙烯酸叔丁酯的核壳复合微粒。
2.
The aim to synthesize the composite microparticles based on silica as core and crosslinked poly(tert-butylmethacrylate) as shell in this work, is to prepare the inorganic/organic core/shell composite microparticles whose shells are composed of crosslinked poly(methacrylic acid) by transforming poly(tert-butylmethacrylate) into poly(methacrylic acid) by hydrolysis.
本文采用种子乳液聚合法制备内核为二氧化硅、壳层为具有交联结构的聚甲基丙烯酸叔丁酯的核壳复合微粒,目的是想通过水解,使聚甲基丙烯酸叔丁酯转变为聚甲基丙烯酸,最后得到壳层为交联聚甲基丙烯酸的无机/有机核壳复合微粒。
4)  tert-butyl-α-methacrylate
α-甲基丙烯酸叔丁酯
5)  tert-butyl methacrylate
甲基丙烯酸叔丁酯
1.
In this study,a homopolymer and a series of copolymers of tert-butyl methacrylate(TBMA) with methacrylic acid(MAA) and styrene(St) were synthesized.
本研究合成了甲基丙烯酸叔丁酯(TBMA)的均聚物及其与甲基丙烯酸(MAA)、苯乙烯(St)的共聚物,并与二乙烯基醚(BPA-DEVE)和光生酸剂(PAG)构成光敏成像体系。
2.
Macro-intermediate with Br-end Poly(tert-butyl methacrylate)(PtBMA-Br) was synthesized by Atom Transfer Radical Polymerization(ATRP),with ethyl-2-bromopropionate as initiator,a compound system of CuCl/ N,N,N′,N″,N″-penta-methyldiethylenetri-amine(PMDETA) as catalyst.
以α-溴代丙酸乙酯(EPN-Br)为引发剂,氯化亚铜(CuCl)与N,N,N′,N″,N″-五甲基二亚乙基三胺(PMDETA)组成的混合体系为催化剂,使甲基丙烯酸叔丁酯(tBMA)进行原子转移自由基聚合(ATRP),得到了端基为溴原子的聚甲基丙烯酸叔丁酯大分子中间体PtBMA-Br。
3.
The diblock copolymer of styrene and tert-butyl methacrylate was synthesized by anionic polymerization at 10 ℃.
在 10℃下 ,采用阴离子聚合方法合成相对分子质量、嵌段组成均可控且相对分子质量分布窄的苯乙烯 -甲基丙烯酸叔丁酯嵌段共聚物 ,对所得共聚物进行了IR、NMR、TG、TEM等表征 ,表明共聚物为嵌段结
6)  tert-butylmethacrylate
甲基丙烯酸叔丁酯
1.
In this paper, a solusion atom transfer radical polymerization (ATRP) of tert-butylmethacrylate (tBMA) was first studied.
本文以α-氯代丙酸乙酯(ECP)为引发剂,2,2′-联二吡啶(bpy)和N,N,N′,N″,N″-五甲基二亚乙基三胺(PMDETA)为配体,氯化亚铜(CuCl)为催化剂,在N,N′-二甲基甲酰胺(DMF)中使甲基丙烯酸叔丁酯(tBMA)进行原子转移自由基聚合(ATRP),考察了不同配体/催化剂条件下tBMA的ATRP反应过程。
2.
Atom transfer radical polymerization(ATRP) of tert-butylmethacrylate(tBMA) was studied using ethyl-2-chloropropionate(ECP) as initiator in DMF.
以α-氯代丙酸乙酯(ECP)为引发剂,N,N,N′,N″,N″-五甲基二亚乙基三胺(PMDE-TA)为配体,在N,N′-二甲基甲酰胺(DMF)溶液中引发甲基丙烯酸叔丁酯(tBMA)进行原子转移自由基聚合(ATRP),调节聚合反应时间得到了端基为氯原子,数均分子量为1。
补充资料:丙烯酸叔丁酯
分子式:C7H12O2
分子量:128.17
CAS号:1663-39-4

性质:密度0.883。熔点-69°C。沸点121°C。折射率1.41-1.412。闪点11°C。水溶性2 g/L。

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