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1)  potential(φ)-pH diagram
电位(φ)-pH图
2)  φ-pH diagram
φ-pH图
1.
Thermodynamics of preparation of ultrafine nickel powders using polyol reduction was studied and plotted theφ-pH diagram of Ni-EG-H_2O.
本论文通过对多元醇还原法的热力学分析,绘制出Ni-EG-H_2O体系的φ-pH图,由φ-pH图预测反应进行的可能性。
3)  potential-pH diagram
电位-pH图
1.
The reaction equilibrium and potential-pH formulas of the In2S3-H2O system are given and the potential-pH diagrams of the system at 25 ℃and 150 ℃ are drawn based on thermodynamic calculation.
通过热力学计算,给出了In2S3-H2O系的反应平衡式及电位-pH的关系式,并绘制了25℃和150℃下In2S3-H2O系的电位-pH图,为含硫化铟的矿物高温氧化浸出提供了一定的热力学数据。
2.
The potential-pH diagram of RE-H2O was also used to investigate the chemical stability of various kinds of RE compound.
热力学计算及电位-pH图表明Ce3+在有氧时可被氧化成沉淀倾向更强的Ce4+,在酸性溶液中Ce4+化合物的稳定性要高于La3+化合物,因此Ce3+的缓蚀效果要好于La3+。
4)  E-pH diagram
电位-pH图
1.
With the thermodynamic analysis and E-pH diagrams for Fe-H_2O,Pd-H_2O and Fe-NH_4~+-H_2O,the thermodynamic analysis for electrodepositing Fe-Pd alloy from the solution was systemically carried out.
7H2O,Pd(NH3)2Cl2和导电盐(NH4)2SO4所组成的溶液体系为研究对象,基于溶液各组成同时处于平衡的热力学原理,通过对Fe-H2O系、Pd-H2O系和Fe-NH4+-H2O系三种体系的热力学分析与计算及其电位-pH图的绘制与分析,对电沉积Pd-Fe合金的溶液进行了较为系统的热力学分析。
5)  Eh-pH diagram
电位-pH图
1.
The significance and application of Eh-pH diagram were reviewed in detail.
阐述了电位-pH图的意义及应用,比较了绘制理论电位-pH图和实验电位-pH图的优劣,着重阐述了理论电位-pH图的绘制步骤及方法,列出了与电位-pH图绘制有关的4类反应。
6)  potential-pH plot
电位-pH图
1.
Basing on many former researchful works, the technology and mechanism of electrodeposition on Pd-Fe alloy film are investigated in our experiments, including the following several main aspects:Firstly, potential-pH plots of Fe-H2O.
绘制了Fe-H_2O系、Pd-H_2O系和Fe-NH_4~+-H_2O系的电位-pH图,进行了相关的热力学分析。
2.
Process and mechanism of electrodeposited Zn-Fe-Si02 composite coatings were studied, including some contents as follow:Potential-pH plots of Zn-H2O and Fe-H2O systems were drawn, and the thermomechanical analysis was made.
本文研究了电沉积Zn-Fe-SiO_2复合镀层的工艺和机理,主要包括以下几个方面: 绘制了Zn-H-2O系和Pe-H_2O系的电位-pH图,并对其进行了热力学分析,结果表明,锌和铁发生共沉积的区域很大,这就对电沉积Zn-Fe合金的可能性提供了理论依据,但是锌和铁的平衡电位差别较大,所以,必须在镀液中添入一定量的配合剂才能使锌铁产生共沉积。
补充资料:实验电位-pH图
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CAS号:

性质:把理论的电位-pH图用金属在酸、碱、氧化性介质中的实际腐蚀与纯化情况加以校正制得的图。这种图与实际情况有很好的对应性,有很大的实用价值。例如在钝化体系中,当含氯离子时,实验图中出现很大的变化。对铁来说,不仅均匀腐蚀的范围扩大了,而且在原来的钝化区中出现了点蚀区和不完全钝化区。

说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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