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1)  4f-3d bimetallic coordination complex
4f-3d双核配合物
2)  4f-3d complex
4f-3d配合物
3)  3d-4f complexes
3d-4f配合物
4)  3d-4f bimetallic complexes
3d-4f异金属配合物
1.
Two 3d-4f bimetallic complexes,{[(bpca)Fe(CN)3Pr(H2O)5]Cl2}n(1) and {[(bpca)2Fe2(CN)6Pr(H2O)6]Cl·4H2O}n(2)(bpca=bis(2-pyridylcarbonyl)amidate anion),have been synthesized and their crystal structures were dete-rmined.
以[(bpca)Fe(CN)3]-(bpca=二(2-吡啶羰基)酰胺阴离子)为构筑基元,设计合成了2个新颖的3d-4f异金属配合物,{[(bpca)Fe(CN)3Pr(H2O)5]Cl2}n(1)和{[(bpca)2Fe2(CN)6Pr(H2O)6]Cl。
5)  binuclear complex
双核配合物
1.
The binuclear complex [Cu 2(TS)(H 2O)]·H 2O, where TS donates the binuclearing ligand derived from the schiff base N,N'_bis(3_carboxylsalicylidene)trimethylenediamine, was obtained through the selfdecomposition of mononuclear complex Na 2CuTS·H 2O in the methanol/water.
利用单核配合物Na2 CuTS·H2 O在溶剂中的不稳定性质 ,自分解并重新组装得到了双核配合物 [Cu2 (TS)(H2 O) ]·H2 O 。
2.
A synthetic method of LnH2salen complexes was described and a series of binuclear complexes were obtained.
合成了稀土N,N-亚乙基双(水杨醛缩亚胺)(H2salen)双核配合物,通过元素分析、热分析、紫外、红外、远红外光谱、磁化率及1H、13CNMR谱与T1的测定,确定了他们与前人合成的配合物有所不同,其化学组成为[Ln2(H2salen)3(NO3)4](NO3)2·3H2O(Ln=La,Pr,Nd,Sm,Gd,Tb,Er,Yb及Y),并对它们的配位作用、波谱及可能应用进行了探讨。
3.
Six new binary complexes Cr(L-A)3[L=H, 2-OCH3, 4-OCH2CH3; A=2-(COO)C6H4CONHC6H4-,COOCH2CH2CONHC6H4-]and four new binuclear complexes Cr(L-A)3?/2CuX2[L=2-OCH3 , 4-OCH2CH3 : X=C1 , Br] were synthesized and characterized by elemental analysis, infrared and ultraviolet spectra as well as molar conductors.
本文报道了六种二元配合物Cr(L-A)_3[L=H,2-OCH_3,4-OCH_2CH_3;A=2-(COO)C_6H_4CONHC_6H_4-,COOCH_2CH_2CONHC_6H_4-]和四种双核配合物Cr(L-A)_3·3/2CuX_2[其中L=2-OCH_3,4-OCH_2CH_3;X=Cl,Br]的合成。
6)  dinuclear complex
双核配合物
1.
Studies on the Spectra of Rare Earth Dinuclear Complexes with o-Phenanthroline Hydrate;
稀土邻菲咯啉双核配合物的光谱研究
2.
By using a tricyanometalate precursor TpFeⅢ(CN)3- (Tp=hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged dinuclear complex, (Tp)FeⅢ(CN)3CuⅡ(bpy)2ClO4·CH3OH (1) (bpy=2, 2′-bipyridine), has been prepared and characterized.
采用[TpFeⅢ(CN)3]-作为构筑基块,合成并表征了一个氰基桥联双核配合物[(Tp)FeⅢ(CN)3CuⅡ(bpy)2]ClO·4CH3OH(1)。
3.
The dinuclear complex[Pb(η2-o-FcCOC6H4COO)(μ2-η2-o-FcCOC6H4COO)(phen)]2·CH3OH is prepared with Pb(OAc)2·3H2O,o-ferrocecarbonyl benzoic sodium(o-FcCOC6H4COONa,Fc=(η5-C5H5)Fe(η5-C5H4))and 1,10-phenanthroline(phen) as materials in the mixing solvent of methanol and ethanol.
3H2O与邻羧基苯甲酰二茂铁钠盐[o-FcCOC6H4COONa,Fc=(η5-C5H5)Fe(η5-C5H4)]和1,10-邻菲啰啉(phen)在甲醇和乙醇的混合溶剂中反应,合成了一个双核配合物[Pb(η2-o-FcCOC6H4COO)(μ2-η2-o-FcCOC6H4COO)(phen)]2。
补充资料:核配合
分子式:
CAS号:

性质:又称核融合。在有性繁殖中的配子间核组分的融合,特别是某些真菌的异核细胞的核的融合。

说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条