1) chiral aminoalkylphenol
手性氨基烷基酚
1.
This paper reviews the last few years developments of chiral aminoalkylphenols synthesis, such as aminoalkylphenols can be obtained from the Betti base.
综述了近几年来手性氨基烷基酚合成的最新研究进展,包括通过无溶剂不对称Mannich反应、亚胺的不对称还原反应合成以及Bettibase衍生物的合成等。
2) chiral aminophenol
手性氨基酚
1.
Development of chiral aminophenol ligands and their derivatives in asymmetric synthesis in the past several years, especially in the application to chiral catalytic alkylation, alkenylation, Michael reaction, aldol reacion, cyclopropanation, etc.
综述了手性氨基酚配体及其衍生物的研究进展,着重介绍其在不对称催化烷基化、烯基化、Michael加成、aldol反应及环丙化等反应中的应用。
3) aminoalkylphenol
氨基烷基酚
1.
Novel chiral aminoalkylphenols (R,R)-6a-d were synthesized by stereoselective reduction with .
将光学纯的(R)-(+)-2-甲基-1-苯基丙胺经不对称诱导反应，使潜手性的（2-羟基-5-甲基苯基）甲基酮、（2-羟基-5-甲基苯基）乙基酮、（2-羟基-5-甲基苯基）正丙基酮和（2-羟基-5-甲基苯基）苯基酮转化为相应的烯胺中间体，再经硼氢化钠还原，得到四种未见报道的手性氨基烷基酚类化合物(R,R)-6a-d{4-甲基-2-[(1R)-1-((1R)-(2-甲基-1-苯基丙胺)烷基)]苯酚（烷基为甲基、乙基、正丙基和苯基），收率为66。
2.
In this paper, from starting materials of p-cresol and corresponding carboxylic acid chlorides or carboxylic acid anhydrides, five novel aminoalkylphenols were synthesized by reactions of esterification, rearrangement, methylation, amination and hydrolysis.
本文以对甲酚和乙酐、丙酰氯、异丁酰氯、苯甲酰氯、苯乙酰氯为原料,经过酯化、重排、甲基化、胺化、水解五步反应首次合成了五种未见报道的氨基烷基酚,即2-(1-氨基乙基)-4-甲基苯酚、2-(1-氨基丙基)-4-甲基苯酚、2-(1-氨基-2-甲基丙基)-4-甲基苯酚、2-(1-氨基苄基)-4-甲基苯酚和2-(1-氨基苯乙基)-4-甲基苯酚。
4) chiral amino acid p nitrophenyl este
手性氨基酸对硝基酚酯
5) m-N,N-dialkylaminophenol
间N,N-二烷基氨基苯酚
6) Chiral amino alcohols
手性氨基醇
1.
The applications and recent progresses of chiral amino alcoholsas either ligands or catalysts in asymmetric synthesis are reviewed.
综述了手性氨基醇作为配体或催化剂在不对称合成中的应用及最新进展。
2.
Chiral amino alcohols are a class of optically active amino alcohols obtained by the reduction of α-amino acids as starting materials.
手性氨基醇是一类由α-氨基酸经过手性源还原得到的具有光学活性的氨基醇。
3.
A series of novel chiral amino alcohols containing benzimidazole group were synthesized by the reaction of D-phenylglycinol with different substituted 2-chlorobenzimidazole which were synthesized by bromination and nitration.
以2-氯苯并咪唑为原料,通过硝化反应和溴化反应,分别合成其硝化和溴化产物;再以二异丙基乙氨为溶剂,和D-苯甘氨醇反应,合成了一系列新型含苯并咪唑手性氨基醇类化合物,并对各产物进行了核磁共振(NMR)、红外(IR)、质谱(MS)表征。
补充资料：4-[(4-氨基-间甲苯基)氨基]酚
CAS: 6219-89-2
分子式: C13H14N2O
中文名称: 4-[(4-氨基-间甲苯基)氨基]酚
英文名称: 4-[(4-amino-3-methylphenyl)amino]-Phenol；p-(4-amino-m-toluidino)-pheno；p-(4-amino-m-toluidino)phenol；4-[(4-amino-3-methylphenyl)amino]-pheno；4-amino-4'-hydroxy-3-methyldiphenylamine
分子式: C13H14N2O
中文名称: 4-[(4-氨基-间甲苯基)氨基]酚
英文名称: 4-[(4-amino-3-methylphenyl)amino]-Phenol；p-(4-amino-m-toluidino)-pheno；p-(4-amino-m-toluidino)phenol；4-[(4-amino-3-methylphenyl)amino]-pheno；4-amino-4'-hydroxy-3-methyldiphenylamine
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条