1) allylic selenide
烯丙基硒醚
1.
Allylic acetates were readily converted to corresponding allylic selenides by reduction with Pd-(PPh 3) 4-SmI 2 and subsequent treatment with arylselenenyl bromides.
醋酸烯丙酯被Pd(PPh3) 4 SmI2 还原 ,并发生中间体π 烯丙基钯络合物的极性反转 ,而后与芳基硒溴化物作用 ,生成烯丙基硒
2) 3-arylselenopropene
烯丙基苯基硒醚
3) vinylic selenides
烯基硒醚
1.
Treatment of polystyrene-supported selenium ,bromide with lithium acetylides afforded polystyrene-supported selenoacetylene, which reacted with dicyclohexylborane giving a way for stereoselective synthesis of polymer-supported (Z)- vinylic selenides.
聚苯乙烯负载硒溴与炔基锂反应合成聚苯乙烯负载炔基硒醚,再与二环己基硼烷反应制得聚苯乙烯负载顺式烯基硒醚;此负载型烯基硒醚在NiCl2(PPh3)2存在下与格氏试剂发生偶联反应,提供了一种有效的(Z)-1,2-二取代乙烯的固相有机合成方法。
4) β-Elemene isopropyl selenide
β-榄香烯异丙基硒醚
5) propargyl selenides
炔丙基硒醚
1.
Promoted by indium, allylic and propargyl bromides react with diorganyl diselenides in THF to give allylic and propargyl selenides in moderate to good yields.
烯丙基溴和炔丙基溴在铟促进下与二硒化合物反应,生成烯丙基和炔丙基硒醚。
6) allyloxy
[,æli'lɔksi]
烯丙基醚
1.
A novel benzoxazine compound,3-(4-allyloxy)phenyl-3,4-dihydro-2H-6-(N-maleimido)-1,3-benzoxazine(AMB),was synthesized.
与传统的3-苯基-3,4-二氢-(N-马来酰亚胺)-1,3-苯并噁嗪(MIB)相比,AMB的分子结构中多了一个烯丙基醚基团。
2.
Benzoxazine with maleimde and allyloxy groups is synthesized by the reaction of allyloxy compounds, maleimide compounds and peraformaldehyde.
含马来酰亚胺和烯丙基醚苯并嗯嗪中间体是由马来酰亚胺化合物、烯丙基醚化合物与多聚甲醛脱水缩合反应而成。
补充资料：二丙二醇基单甲基单烯丙基醚
CAS：79313-21-6
中文名称：二丙二醇基单甲基单烯丙基醚
英文名称：Dipropylene glycol monomethyl monoallyl ether
中文名称：二丙二醇基单甲基单烯丙基醚
英文名称：Dipropylene glycol monomethyl monoallyl ether
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条