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1)  aryldibromide
二溴代芳烃
2)  1,1-dibromoalkene
1,1-二溴代芳烯烃
3)  aryl bromide
溴代芳烃
1.
Suzuki cross-coupling reactions between aryl bromides and phenylboronic acids were studied over a hydroxyapatite-supported Mn catalyst(MnHAP) for the first time.
对于不同取代基取代的溴代芳烃或苯硼酸,可以得到中等产率(18%~46%)的偶联产物。
2.
The palladium catalyst supported on fluoride pillared layered double hydroxide(LDH-F) was prepared by the incipient wetness method,and it was used to catalyze the Heck and Suzuki coupling reactions of aryl bromides.
以氟离子插层的水滑石LDH-F为载体,用逐滴浸渍法制备了新型Pd/LDH-F催化剂,并用其催化溴代芳烃的Heck和Suzuki偶联反应。
4)  polycyclicaryl bromide
多环溴代芳烃
1.
A new and facile one pot preparation of polycyclicarylboronic acid is described,using BF\-3·OEt\-2,polycyclicaryl bromide and magnesium turnings(mol ratio 1∶1∶1) as starting substrates and reacting at 35 ℃ to give mono substituted boronic acid in 40%-60% yield(purity 98%-99%).
选择BF3·OEt2 作为硼化试剂 ,与多环溴代芳烃、Mg粉 (物质的量比 1∶1∶1 )在 35℃“一锅”反应 5h来制备单取代硼酸 ,可以获得40 %~ 60 %的产率 ,产物质量分数为 98%~ 99%。
5)  ω-dibromoalkane
ω-二溴代烷烃
1.
A series of α,ω-bis(4-methylphenoxyl) alkanes were synthesized by the nucleophilic substituted reaction of the salts of p-cresol and α,ω-dibromoalkanes with ethanol or water as solvent,and then reacted with N-bromosuccinimide to produce α,ω-bis(4-bromomethylphenoxyl) alkanes.
以乙醇或水为反应介质,通过对甲酚盐与α,ω-二溴代烷烃的亲核取代反应合成了α,ω-二(4-甲基苯氧基)烷烃系列产品,并以N-溴代丁二酰亚胺(NBS)作溴化试剂合成得到α,ω-二(4-溴甲基苯氧基)烷烃;通过元素分析和1H NMR等方法对目标化合物的结构进行了表征。
6)  α,ω-dibromoalkanes
α,ω-二溴代烷烃
补充资料:3,5-二溴-N-(4-溴代苯基)-2-羟基苯甲酰胺
分子式:C13H8Br3NO2
分子量:449.96
CAS号:87-10-5

性质:无色至浅棕色针状结晶。熔点227-228℃。易溶于二甲基甲酰胺,溶于热丙酮,微溶于乙醇,不溶于水。

制备方法:由水杨酰苯胺溴化而得。

用途:用于制造消毒药皂(中性皂中含本品0.3-0.5%),可用于防治皮肤病、医院消毒洗涤液。也可作为化妆品的防腐剂。

说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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