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1)  terminal epoxides
末端环氧化合物
1.
In the presence of 5-10 mol % of 2, a series of terminal epoxides were reacted with phthalimide to form the ring-opening products, which, on treating with hydrazine to give 13 ? aminoalcohols in moderate yield.
以二乙胺和三光气为原料合成四乙基脲1,1进一步与五氯化磷及叔丁胺作用得到1,1,3,3-四乙基-2-叔丁基胍2,以5-10mol%2为催化剂,可实现邻苯二甲酸亚胺对一系列末端环氧化合物的开环,所得产物肼解后得β—氨基醇,产率适中。
2)  chiral terminal epoxide
手性末端环氧化合物
1.
Chiral β-amino alcohol and β-alkoxyl alcohol derivatives which are biologically important could be obtained by the ring-opening reactions of chiral terminal epoxides with amines and alkoxy anions.
用手性 (Salen)Co催化剂催化的外消旋末端环氧化合物的水解动力学拆分反应所得的手性末端环氧化合物和各种取代的胺和烷氧负离子反应 ,可得到光学纯的 β 胺基醇和 β 烷氧基醇类化合物 ,这两类化合物是重要的生物活性分子 。
3)  4,4-diphenylsubstituted terminal alkene epoxide
4,4-二苯基取代末端环氧化合物
1.
1,1-Diphenylalkyllithium, obtained from the reaction of the corresponding alkyllithium with 1,1-diphenylethylene, reacted with optically active epichlorohydrin at -70 ℃, then at room temprature under stirring for several hours to yield chirally pure 4,4-diphenylsubstituted terminal alkene epoxide with >90% ee.
烷基锂先与1,1-二苯乙烯反应生成相应的1,1-二苯烷基锂,接着在-70℃下滴加手性环氧氯丙烷,然后回到室温搅拌几小时,按常法处理后,得到手性纯的4,4-二苯基取代末端环氧化合物,它们的ee值均大于90%,此外还对反应机理进行了讨论。
4)  composite oxide powder
复合氧化物粉末
1.
Study on phase transformation of(W,Ni,Fe) composite oxide powder in H_2-reduction process;
氢气还原(W,Ni,Fe)复合氧化物粉末的物相变化研究
2.
Reduction procedure study on W-Ni-Fe composite oxide powder;
W-Ni-Fe复合氧化物粉末的还原工艺
3.
Fe-18 Cr-9 W Nanometer composite powder was produced by the method of co-reduction of Fe-18 Cr-9 W composite oxide powder,in which the procedure parameters were controlled.
通过H2—CO共还原法对Fe—18Cr—9W复合氧化物粉末进行还原,控制还原工艺的参数制得纳米级Fe—18Cr—9W复合粉末。
5)  Tenonal epoxides
端位环氧化物
6)  terminal enzyme
末端氧化酶
补充资料:(甲基环氧乙烷与环氧乙烷的聚合物)的单十四醚
CAS:37311-04-9
分子式:C14H30O·(C3H6O·C2H4O)x
中文名称:(甲基环氧乙烷与环氧乙烷的聚合物)的单十四醚
英文名称:Oxirane, methyl-, polymer with oxirane, monotetradecyl ether
oxirane, methyl-, polymer with oxirane, monotetradecyl ether
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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