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1)  hydrazinolysis ring-opening reaction
肼解开环反应
2)  hydrazinolysis [haidrəzi'nɔlisis]
肼解反应
1.
Hydrazinolysis of methyl 2-ethoxybenzoate with hydrazine hydrate was first carried out to obtain 2-methoxybenzol hydrazine(1); hydrazinolysis was then performed between ethyl butyrimidate hydrochloride and 1 to produce 2-ethoxy-N′-(1-iminobutyl)benzohydrazide hydrochloride(3); 3 was finally cyclized with chloroacetone to give 4.
2-乙氧基苯甲酸甲酯与水合肼发生肼解反应生成2-甲氧基苯甲酰肼(1);1与丁亚氨酸乙酯盐酸盐进行二次肼解反应制得2-乙氧基-N′-(1-亚胺丁基)苯甲酰肼盐酸盐(3);3与氯丙酮环化合成了2-乙氧基-N-(4-甲基-2-丙基-1H-咪唑基-1-)苯甲酰胺(合成伐地那非的关键中间体),总收率48%,其结构经1H NMR和MS确证。
3)  Ring-opening reaction
开环反应
1.
Potassium maleate-containing ionomers were prepared by ring-opening reaction of epoxidized styrene-butadiene-styrene block copolymer(SBS).
用环氧化(苯乙烯-丁二烯-苯乙烯)嵌段共聚物(SBS)开环反应合成了含顺丁烯二酸钾基的SBS离聚体,考察了离子基团不同含量对含顺丁烯二酸钾基的SBS离聚体力学性能的影响,研究了离聚体/聚丙烯(PP)共混物的力学性能和耐溶剂性能,以及离聚体对氯醇橡胶(CHR)/SBS共混物的增容效果。
2.
Epoxidized styrene-butadiene-styrene triblock copolymer(ESBS) can react with potassium hydrogen maleate by ring-opening reaction in the presence of phase transfer catalyst and ring-opening catalyst.
利用环氧化苯乙烯-丁二烯-苯乙烯嵌段共聚物(ESBS)的环氧基与顺丁烯二酸氢钾(HKM)在相转移催化剂和开环催化剂存在的条件下开环反应制得钾离聚体。
3.
Sodium sulfonated SBS ionomer was made from epoxidized styrene-butadienestyrene triblock copolymer(ESBS) and NaHSO_3 by ring-opening reaction in the presence of phase transfer catalyst,ring-opening catalyst and pH value regulator.
结果表明,ESBS开环反应制备磺酸钠离聚体的最佳条件为:ESBS在甲苯中的质量浓度为12 g/100 mL;n(NaHSO3)/n(Epoxy)=1。
4)  Ring-opening
开环反应
1.
The present work use a new-type anode, lead dioxde membrane electrode,for electron-chemically oxidizing calcium lignosulfonate, and discuss the effects of pH value, electrolysisvoltage and charge amount on aromaic ring-opening reaction of lignin during the process of elec-tro-oxidation, Some conclusions are obtained from the results.
用一种新型电极—PbO2膜电极作阳极对本质素磺酸盐溶液进行电氧化反应,研究中发现在电氧化过程中木质素磺酸盐除发生分子链断裂之外,芳香环开环反应也很显著。
5)  ring opening reaction
开环反应
1.
Ab initio study on the ring opening reactions of cyclopropymethanide and cyclobutylmethanide;
环丙烷及环丁烷甲基化合物开环反应机理的从头算研究
2.
Their ring opening reactions can be used for preparing polyfunctional or other cyclic compounds.
环氧烷化合物的开环反应可以用来合成其它方法难以合成的多官能团化合物 ,或通过开环和修饰合成其他环状化合物。
3.
This article reviews the ring opening reaction of five membered nitrogen containing heterocyclic compounds.
综述了近年来各种五元氮杂环的开环反应及其在有机合成中的应用。
6)  ring opening metathesis polymerzation
开环复分解聚合反应
补充资料:硝酸、环十二烷醇、环十二烷酮的反应产物高沸点馏分
CAS: 72162-23-3
分子式: C12H24O·C12H22O·HNO3
熔点: 85-95℃
中文名称: 硝酸、环十二烷醇、环十二烷酮的反应产物高沸点馏分

英文名称: Nitric acid, reaction products with cyclododecanol and cyclododecanone, by-products from, high-boiling fraction
Cyclododecanol, cyclododecanone, nitric acid reaction product, high-boiling fraction
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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