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1)  isotope exchange technique
同位素交换技术
1.
Using 13CO2-CO isotope exchange technique, the rate constant of CO2 dissociation on the surface of molten oxide containing iron oxide can be accurately measured, and the kinetic process also can be analyzed and discussed.
采用13CO2-CO同位素交换技术,可以准确测定CO2在液态氧化物熔渣表面的分解反应速率常数以及分析反应的动力学过程。
2)  isotopic exchange
同位素交换
1.
The results of isotopic exchange of(()~(18)O),temperature-programmed surface reaction of ethanol(C_2H_5OH-TPSR),temperature-programmed desorption of CO(CO-TPD),and temperature-programmed reduction of H_2(H_2-TPR) show that the Pt phase is amorphous and well dispersed on the support surface.
25O2催化剂,考察了催化剂对乙醇及CO的氧化活性,并采用18O同位素交换、乙醇程序升温表面反应(C2H5OH-TPSR)、一氧化碳程序升温脱附(CO-TPD)和程序升温还原(H2-TPR)等技术对催化剂进行了表征。
2.
Recovering deuterium from uranium deuteride bed by means of the isotopic exchange reaction between the solid and gas phases at room temperature is introduced.
研究了氢气经过流通式氘化铀床,利用气-固相之间的同位素交换反应回收床中的氘。
3)  isotope exchange
同位素交换
1.
This paper presents main specific properties of a few hydrophobic catalysts made by ourselves with which isotope exchange experiments of H-T at atmospheric temperature are made.
本文简要介绍了自制的几种疏水催化剂的主要特性,采用这些催化剂进行了室温下的H—T同位素交换实验,初步考察了氢气流速对催化活性的影响。
2.
For this purpose, we have investigated the isotope exchange process for the trace recovery from the imitative residue of the alloy.
利用同位素交换法对模拟液态锂铅合金残渣中的微量氚进行回收。
3.
High temperature solid state catalytic isotope exchange reaction provides a new effective method for the preparation of tritium of labelled organic compounds which have high specific activity and bioactivity.
高温固态催化同位素交换法为制备具有生物活性的高放射性比活度的氚标记有机化合物提供了新的途径。
4)  isotopic technique
同位素技术
1.
Isotopic technique is a rapid, accurate, sensitive and reliable way to trace the substance exchange process inside a system or between two systems, particular in tracing the origin of substance entering a system, which make it unexampled and widely applied in life science, environmental science and other areas.
同位素技术具有快速、准确、灵敏、可靠等特点,可以跟踪系统內外物质交换过程和追踪参与交换物质的最初来源,在某些方面是其他方法无可比拟的。
5)  isotope technique
同位素技术
1.
The functions of environmental isotope techniques and the main problems occurred in their applications to tunneling are presented.
本文基于资料调研及工程实践 ,论述了隧道工程勘测和施工过程中开展环境同位素研究的必要性 ,介绍了环境同位素技术的作用及其在隧道工程应用中存在的主要问题 ,并强调指出为提高我国隧道勘测水平 ,今后应重视和加强同位素技术在隧道地下水环境中的应用研
6)  H-D isotopic exchange
H-D同位素交换
1.
The D_2 pulse reaction results over Co-CeO_2/SiO_2 and Co/SiO_2 catalysts showed that the addition of CeO_2 increased the catalytic activity of Co/SiO_2 for the H-D isotopic exchange and the reactivity of H from Si-OH for CO hydrogenation.
通过比较在Co-CeO2/SiO2和Co/SiO2催化剂上的脉冲D2反应实验结果发现,CeO2可以提高载体表面Si-OH的H-D同位素交换活性和Si-OH中H参与CO加氢反应的活性;CeO2不仅增加了催化剂表面活性碳物种的总量,而且活性碳物种以链增长单体-CH2-为主,因而有利于增加费托合成反应速率和链增长几率;CeO2的加入明显提高了催化剂表面碳原子的加氢反应速率,从而减少了碳沉积。
补充资料:同位素交换反应平衡
分子式:
CAS号:

性质:两种(或更多种)分子间同一元素的同位素相互交换位置的反应叫同位素交换反应,其特点是反应可逆。对于交换反应Ax+Bx*Ax*+Bx(x和x*分别代表某一元素轻、重同位素),正向反应速度V=K[Ax]·[Bx*],逆向反应速度V=K[Ax*][Bx](K和K分别代表正向反应和逆向反应的速度常数)。反应开始时,V>V;随着反应的进行,V逐渐减小,V逐渐增大,当V=V时,反应达到平衡,此种平衡称为同位素交换反应平衡。

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