1) New vanadium complexes
有机钒氧配合物
2) organically carboxylate oxovanadium coordination compounds
有机羧酸氧钒配合物
1.
Six organically carboxylate oxovanadium coordination compounds were synthesized and their chemical structures were determined by elemental analysis,IR,UV,MS, 1H-NMR.
合成了苯甲酸氧钒 (1)、丙二酸氧钒钠 (2 )、阿司匹林氧钒 (3)、3 ,5 二异丙基水杨酸氧钒(4 )、酒石酸氧钒 (5 )和乙酰丙酮氧钒 (6 ) 6个新型的有机羧酸氧钒配合物 ,其中 3个未见文献报道。
4) Vanadium complex
钒氧配合物
1.
The new vanadium complexes VO(acac)(HB(pz)3)(1) and VO(acac) (HB(3,5-Me2pz)3) ·CH3CN(2) with poly-pyrazolylborate as the ligand were synthesized.
合成了2种以聚类吡唑硼酸盐配体的钒氧配合物,VO(acac)(HB(pz)3)(1)和VO(acac)-(HB(3,5- Me2pz)3)·CH3CN(2)。
5) oxovanadium complex
氧钒配合物
1.
The inhibitory activities against PTP1B and alkaline phosphatase (ALP) by oxovanadium complexes with 2,2\'-biimidazole (L1), 2,2\'-bipyridine (L2) and 1,10-phenanthroline (L3) have been investigated in vitro.
研究了三种含氮平面杂环螯合配体2,2\'-联咪唑(L1),2,2\'-联吡啶(L2),1,10-邻菲咯啉(L3)的氧钒配合物对PTP1B以及碱性磷酸酶(alkaline phosphatase,ALP)的体外抑制作用。
6) diperoxovanadate
双过氧钒配合物
1.
NMR Studies on Interactions between Diperoxovanadate and 1-Ethyl-1H-Imidazole
双过氧钒配合物与N-乙基咪唑相互作用的NMR研究
2.
To understand the effects of organic ligands of the diperoxovanadate complexes on the reaction equilibrium,the interactions between a series of diperoxovanadate complexes [OV(O2)2LL']n- [n=1～3;LL'=oxalate,abbr.
15mol/L NaCl溶液),应用多核(1H,13C和51V)多维(COSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)2LL']n-[n=1～3,LL'=oxalate(缩写为oxa)、picolinate(缩写为pic)、bipyridine(缩写为bipy)和1,10-phenanthroline(缩写为phen),与它们配位的含钒物种分别缩写为bpV(oxa),bpV(pic),bpV(bipy)和bpV(phen)]与N-甲基咪唑(缩写为N-Me-Im)的相互作用,实验结果表明N-Me-Im与4种双过氧钒配合物的反应活性从强到弱的顺序为:bpV(oxa)>bpV(pic)>bpV(bipy)>bpV(phen)。
3.
To understand the substituting effects of organic ligands on the reaction equilibrium, the interac- tions between diperoxovanadate complex [OV(O2)2(D2O)]-/[OV(O2)2(HOD)]- and a series of N-substituted picolinamide ligands in solution were explored using multinuclear (1H, 13C, and 51V) magnetic resonance, COSY, DOSY, and variable temperature NMR in 0.
15mol/LNaCl溶液),应用多核(1H,13C和51V)多维(COSY和DOSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)2(D2O)]-/[OV(O2)2(HOD)]-与N-取代皮考啉酰胺的相互作用。
补充资料：有机
1.原指与生物体有关的或从生物体来的(化合物)﹐现指除一氧化碳﹑二氧化碳﹑碳酸﹑碳酸盐和某些碳化物之外﹐含碳原子的(化合物)。 2.指事物构成的各部分互相关连﹐具有不可分的统一性。 3.有机会。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条