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1)  2-aminothiophenes
2-氨基噻吩衍生物
2)  ethyl 2-amino-6-methyl-5,7-diphenyl-4,5,6,7-tetrahydrothieno pyridine-3-carboxylate
2-氨基四氢吡啶并噻吩衍生物
1.
Then,1-methyl-2,6-diphenylpiperidin-4-one is synthesized using 1,5-diphenylpenta-1,4-dien-3-one and methylamine,At last,Gewald reaction was utilized to obtain ethyl 2-amino-6-methyl-5,7-diphenyl-4,5,6,7-tetrahydrothieno pyridine-3-carboxylate through the reaction of 1-methyl-2,6-diphenylpiperidin-4-one with ethyl cynoacetate and sulfur in the presence of morpholine.
首先利用醛酮缩合制得二烯酮(1),然后利用1与甲胺溶液作用制得哌啶酮(2),最后利用Gewald反应使2、氰乙酸乙酯与硫磺在吗啡啉催化下,得到未见文献报道的2-氨基四氢吡啶并噻吩衍生物3,产率60%~80%。
3)  2-aminothiazole derivative
2-氨基噻唑衍生物
1.
Nine 2-aminothiazole derivatives were obtained under microwave irradiation condition by the reaction of thiourea, iodine and ketone in the absence of solvent.
在无溶剂条件下,用微波辐射法以碘、酮和硫脲为原料合成了9个2-氨基噻唑衍生物。
4)  Thiophene derivatives
噻吩衍生物
1.
High regioselective preparation of mono-bromothiophene derivatives
高选择性地制备单溴代噻吩衍生物
2.
Two new thiophene derivatives 5,8-dithiophenyl-acenaphthenequinoxaline(DThQx(ace)) and 3,6-dithiophenyl-pyridazine(DThPD) were prepared using tetra(triphenylphosphine) palladium(Pd(PPh_3)_4) as catalyst.
在四(三苯基膦)钯(Pd(PPh3)4催化作用下,通过催化偶合法可合成5,8-二噻基-萘基喹喔啉(DThQx(ace))和3,6-二噻基-哒嗪(DThPD)两种新型噻吩衍生物,同时也可合成了4,7-二噻基-2,1,3-苯并噻二唑(DThB)和1,4-二噻基-苯(DThPh),上述化合物产率分别为75%,78%,82%和67%。
3.
Three soluble alternating conjugated copolymers P1, P2 and P3, comprised of 9,9-dihexylfluorene and thiophene derivatives with/without oxadiazole side chains, were synthesized via the palladium-catalyzed Suzuki coupling reaction.
设计并通过Suzuki反应合成了三种芴与噻吩衍生物的交替共聚物P1、P2和P3,并主要研究了噁二唑侧链对共聚物的热稳定性、光物理、电化学和光伏性质的影响。
5)  thiophene derivative
噻吩衍生物
1.
However,with the increase of the number of the branched chain on the thiophene ring,the di-and tri-alkylation capability of thiophene derivatives decreased a l.
但噻吩衍生物与己烯进行二次以至多次烷基化反应的能力则随着噻吩环上支链的增加逐渐减弱,原因可能来自噻吩衍生物继续进行烷基化反应的热力学条件不利,以及环上已有侧链的空间位阻效应。
6)  thiophenine [θaiə'feni:n]
2-氨基噻吩
补充资料:[3-(aminosulfonyl)-4-chloro-N-(2.3-dihydro-2-methyl-1H-indol-1-yl)benzamide]
分子式:C16H16ClN3O3S
分子量:365.5
CAS号:26807-65-8

性质:暂无

制备方法:暂无

用途:用于轻、中度原发性高血压。

说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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